Novel activated carbon materials are being constantly developed and applied in many research and industrial applications. The choice of the precursor represents a key step, to achieve satisfying resulting features in terms of surface development, structural features, carbon contents, and amount of ash. In this work, a novel carbon product has been obtained starting from an electrospun b-cyclodextrin/pyromellitic dianhydride linked nanosponge. After the pyrolysis, the polymeric mat resulted in carbon material still displaying fibrous morphology, characterized by a diameters distribution of 1.3 ± 0.5 mm. A peculiar granular microstructure was observed via FESEM, a 692m2/g surface area and a 5e12 Å pore size dis- resulted after z potential analysis. These results confirmed b-cyclodextrin/PMDA-linked electrospun tribution, with pore volume of 0.14 cm3/g, resulted via BET characterization, while ?32.8 ± 0.7 mV nanosponges as a suitable precursor for a novel carbon material preparation.

Microfibers of microporous carbon obtained from the pyrolysis of electrospun β-cyclodextrin/pyromellitic dianhydride nanosponges

Cecone, Claudio;Zanetti, Marco;Anceschi, Anastasia;Caldera, Fabrizio;Trotta, Francesco;Bracco, Pierangiola
2019-01-01

Abstract

Novel activated carbon materials are being constantly developed and applied in many research and industrial applications. The choice of the precursor represents a key step, to achieve satisfying resulting features in terms of surface development, structural features, carbon contents, and amount of ash. In this work, a novel carbon product has been obtained starting from an electrospun b-cyclodextrin/pyromellitic dianhydride linked nanosponge. After the pyrolysis, the polymeric mat resulted in carbon material still displaying fibrous morphology, characterized by a diameters distribution of 1.3 ± 0.5 mm. A peculiar granular microstructure was observed via FESEM, a 692m2/g surface area and a 5e12 Å pore size dis- resulted after z potential analysis. These results confirmed b-cyclodextrin/PMDA-linked electrospun tribution, with pore volume of 0.14 cm3/g, resulted via BET characterization, while ?32.8 ± 0.7 mV nanosponges as a suitable precursor for a novel carbon material preparation.
2019
Inglese
Esperti anonimi
161
277
282
6
https://www.sciencedirect.com/science/article/pii/S0141391019300461
Microporous carbon, Carbon microfibers, Electrospinning, Pyrolysis, Nanosponges, Cyclodextrins
no
3 – prodotto con deroga per i casi previsti dal Regolamento (allegherò il modulo al passo 5-Carica)
262
6
Cecone, Claudio; Zanetti, Marco; Anceschi, Anastasia; Caldera, Fabrizio; Trotta, Francesco; Bracco, Pierangiola
info:eu-repo/semantics/article
partially_open
03-CONTRIBUTO IN RIVISTA::03A-Articolo su Rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/1691694
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