The dehydrogenation of propane was studied in gas-phase at 773 K over two series of silica-deposited Ir–Sn systems: the bimetallic catalysts obtained from Ir–Sn carbonyl clusters precursors and the ones prepared by deposition of a metallorganic Sn precursor onto preformed Ir nanoparticles. In the comparison, cluster-derived catalysts showed good propane conversion, optimal selectivity to propene and high stability under the severe reaction conditions.

Catalytic dehydrogenation of propane over cluster-derived Ir-Sn/SiO2 catalysts

GIANOTTI, Enrica;
2006-01-01

Abstract

The dehydrogenation of propane was studied in gas-phase at 773 K over two series of silica-deposited Ir–Sn systems: the bimetallic catalysts obtained from Ir–Sn carbonyl clusters precursors and the ones prepared by deposition of a metallorganic Sn precursor onto preformed Ir nanoparticles. In the comparison, cluster-derived catalysts showed good propane conversion, optimal selectivity to propene and high stability under the severe reaction conditions.
2006
112
89
95
propane dehydrogenation - bimetallic catalysts - iridium–tin - cluster-derived catalysts - gas-phase
V. DAL SANTO; A. GALLO; E. GIANOTTI; M. GUIDOTTI; G. PELI; R. PSARO; L. SORDELLI
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/6099
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