The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5)2(CO)4] and [ Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(µ-H)(CO)10(µ-OR)], previously inaccessible by thermal routes.
Titolo: | Synthesis of the Alkoxo(hydrido)-clusters [Ru3(m-H)(CO)10(m-OR)] [R = Me, Et, Prn, Bun ] catalysed by Dinuclear Carbonyl Iron Complexes | |
Autori Riconosciuti: | ||
Autori: | Aime, Silvio; Botta, Mauro; Gobetto, Roberto; Osella, Domenico; Franco, Padovan | |
Data di pubblicazione: | 1987 | |
Abstract: | The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5)2(CO)4] and [ Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(µ-H)(CO)10(µ-OR)], previously inaccessible by thermal routes. | |
Volume: | - | |
Pagina iniziale: | 253 | |
Pagina finale: | 254 | |
Digital Object Identifier (DOI): | 10.1039/dt9870000253 | |
Parole Chiave: | cluster; ruthenium; iron; catalysis; ligand substitution | |
Rivista: | JOURNAL OF THE CHEMICAL SOCIETY DALTON TRANSACTIONS | |
Appare nelle tipologie: | 03A-Articolo su Rivista |
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