The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5)2(CO)4] and [ Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(µ-H)(CO)10(µ-OR)], previously inaccessible by thermal routes.
Synthesis of the Alkoxo(hydrido)-clusters [Ru3(m-H)(CO)10(m-OR)] [R = Me, Et, Prn, Bun ] catalysed by Dinuclear Carbonyl Iron Complexes
AIME, Silvio;BOTTA, Mauro;GOBETTO, Roberto;OSELLA, Domenico;
1987-01-01
Abstract
The use of dinuclear carbonyl iron complexes, namely [Fe2(η5-C5H5)2(CO)4] and [ Fe2(CO)4(PPh3)2(SMe)2], as catalysts in reactions of CO replacement by the weak nucleophilic molecules ROH (R = Me, Et, Prn, or Bun) allows the isolation of the novel series of derivatives [Ru3(µ-H)(CO)10(µ-OR)], previously inaccessible by thermal routes.
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