The most important spectroscopic features in the UV-Vis of framework and extraframework Ti(IV) in titanium silicalite are briefly summarized. The spectroscopic manifestations of the complexes formed by framework Ti(IV) in presence of H202 are reported. The formation of EPR active species is also considered.
DRS UV-Vis and EPR spectra of hydroperoxo and superoxo complexes in Titanium Silicalite
BORDIGA, Silvia;ZECCHINA, Adriano;GIAMELLO, Elio;
1993-01-01
Abstract
The most important spectroscopic features in the UV-Vis of framework and extraframework Ti(IV) in titanium silicalite are briefly summarized. The spectroscopic manifestations of the complexes formed by framework Ti(IV) in presence of H202 are reported. The formation of EPR active species is also considered.
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