The infrared frequency and intensity values of the main vibrational modes of selected examples of hydrocarbon ligands bonded to metals are reported. Despite the approximations on the vibrational analysis, the data offer fundamental information on structure, bonding, and reactivity of the metal-ligand unit, successfully comparable with those obtained by other sources (structural analysis, nmr spectroscopy, MO calculation). A future extension of this topic to the study of the adsorbate surface interaction is proposed, in light of the well-known cluster-surface analogy.
How to use the vibrational data for a better understanding of bonding structure and reactivity of organometallic complexes
DIANA, Eliano;
1993-01-01
Abstract
The infrared frequency and intensity values of the main vibrational modes of selected examples of hydrocarbon ligands bonded to metals are reported. Despite the approximations on the vibrational analysis, the data offer fundamental information on structure, bonding, and reactivity of the metal-ligand unit, successfully comparable with those obtained by other sources (structural analysis, nmr spectroscopy, MO calculation). A future extension of this topic to the study of the adsorbate surface interaction is proposed, in light of the well-known cluster-surface analogy.
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