Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal–metal and pi–pi interactions on their energy.
Resonant X-ray emission spectroscopy reveals d–d ligand-field states involved in the self-assembly of a square-planar platinum complex
GARINO, Claudio;Gallo, Erik;GOBETTO, Roberto;LAMBERTI, Carlo;
2012-01-01
Abstract
Resonant X-ray Emission Spectroscopy (RXES) is used to characterize the ligand field states of the prototypic self-assembled square-planar complex, [Pt(tpy)Cl]Cl (tpy=2,2′:6′,2′′-terpyridine), and determine the effect of weak metal–metal and pi–pi interactions on their energy.
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12RXES_Pt_terpy.pdf
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Pttpy_RIXS.pdf
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