The retention properties of a SBA-15 mesoporous silica functionalized with -(CH2)3COOH groups, synthesized by a co-condensation route, were investigated for the ion chromatography of different cationic species. A systematic study on the effect of different eluent compositions containing non-complexing (methanesulfonic acid) or complexing (oxalic or pyridine-2,6-dicarboxylic acids) eluents, in the presence of organic modifiers (CH3CN, CH3OH, CH3NH2) on the retention of cations (Li+, Na+, K+, Ca2+, Mg2+, Sr2+, Ba2+, NH4+, Cu2+, Ni2+, Zn2+, Cd2+, Co2+, Pb2+, Fe3+) chosen as model analytes and for their environmental importance, allowed us to elucidate the mechanisms (cation-exchange or complexation) involved in the retention on the SBA-15 phase. For the first time separations of cations on SBA-15 based stationary phases are investigated, providing the basis for further development of mesoporous silica chemistry for in-flow ion-exchange applications.

Functionalised SBA-15 mesoporous silica in ion chromatography of alkali, alkaline eartths, ammonium and transition metal ions

BRUZZONITI, Maria Concetta;DE CARLO, Rosa Maria;SARZANINI, Corrado
2009-01-01

Abstract

The retention properties of a SBA-15 mesoporous silica functionalized with -(CH2)3COOH groups, synthesized by a co-condensation route, were investigated for the ion chromatography of different cationic species. A systematic study on the effect of different eluent compositions containing non-complexing (methanesulfonic acid) or complexing (oxalic or pyridine-2,6-dicarboxylic acids) eluents, in the presence of organic modifiers (CH3CN, CH3OH, CH3NH2) on the retention of cations (Li+, Na+, K+, Ca2+, Mg2+, Sr2+, Ba2+, NH4+, Cu2+, Ni2+, Zn2+, Cd2+, Co2+, Pb2+, Fe3+) chosen as model analytes and for their environmental importance, allowed us to elucidate the mechanisms (cation-exchange or complexation) involved in the retention on the SBA-15 phase. For the first time separations of cations on SBA-15 based stationary phases are investigated, providing the basis for further development of mesoporous silica chemistry for in-flow ion-exchange applications.
2009
1216
29
5540
5547
Ion chromatography; metals; mechanisms
M.C. Bruzzoniti; R.M. De Carlo; S. Fiorilli; B. Onida; C. Sarzanini
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/131699
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