The synthesis and structural characterization of a new coordination polymer [Pb(OH)]n[Ag(SCN)(CN)]n, formed by an anionic layer [Ag(CN)(µ3-SCN)]nn- linked to the 1D cationic fragment [Pb(OH)]n through a bridging cyanide is reported. We have obtained a rational combination of the pattern of laurionite-type structures ( Pb(OH)X, with X=halogen, SCN) with the 2D hexagonal pattern of the silver thiocyanate. The title compound shows luminescent behaviour, and the analysis of the computed band structure allow us to describe the electronic transitions.

A new heterometallic multiligand 3D coordination polymer: synthesis and structure of [Pb(OH)]n[Ag(SCN)(CN)]n.

DIANA, Eliano;GERVASIO, Giuliana;PRIOLA, EMANUELE;BONOMETTI, Elisabetta
2014

Abstract

The synthesis and structural characterization of a new coordination polymer [Pb(OH)]n[Ag(SCN)(CN)]n, formed by an anionic layer [Ag(CN)(µ3-SCN)]nn- linked to the 1D cationic fragment [Pb(OH)]n through a bridging cyanide is reported. We have obtained a rational combination of the pattern of laurionite-type structures ( Pb(OH)X, with X=halogen, SCN) with the 2D hexagonal pattern of the silver thiocyanate. The title compound shows luminescent behaviour, and the analysis of the computed band structure allow us to describe the electronic transitions.
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http://pubs.rsc.org/en/journals/journalissues/ce#!recentarticles&all
crystal egineering; COORDINATION POLYMERS
Eliano Diana; Giuliana Gervasio; Emanuele Priola; Elisabetta Bonometti
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/151993
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