The effect of a local proton source on the activity of a bromotricarbonyl Mn redox catalyst for CO2 reduction has been investigated. The electrochemical behaviour of the novel complex [fac-Mn(dhbpy)(CO)3Br] (dhbpy = 4-phenyl-6-(1,3-dihydroxybenzen-2-yl) 2,20-bipyridine), containing two acidic OH groups in the proximity of the metal centre, under a CO2 atmosphere showed a sustained catalysis in homogeneous solution even in the absence of Brønsted acids.
Titolo: | A local proton source in a [Mn(bpy-R)(CO)3Br]-type redox catalyst enables CO2reduction even in the absence of Brønsted acids | |
Autori Riconosciuti: | ||
Autori: | Franco, Federico; Cometto, Claudio; Vallana, Federico Ferrero; Sordello, Fabrizio; Priola, Emanuele; Minero, Claudio; Nervi, Carlo; Gobetto, Roberto | |
Data di pubblicazione: | 2014 | |
Abstract: | The effect of a local proton source on the activity of a bromotricarbonyl Mn redox catalyst for CO2 reduction has been investigated. The electrochemical behaviour of the novel complex [fac-Mn(dhbpy)(CO)3Br] (dhbpy = 4-phenyl-6-(1,3-dihydroxybenzen-2-yl) 2,20-bipyridine), containing two acidic OH groups in the proximity of the metal centre, under a CO2 atmosphere showed a sustained catalysis in homogeneous solution even in the absence of Brønsted acids. | |
Volume: | 50 | |
Pagina iniziale: | 14670 | |
Pagina finale: | 14673 | |
Digital Object Identifier (DOI): | 10.1039/C4CC05563B | |
Rivista: | CHEMICAL COMMUNICATIONS | |
Appare nelle tipologie: | 03A-Articolo su Rivista |
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