We report the structure of the Zr metalorganic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects.
Detailed Structure Analysis of Atomic Positions and Defects in Zirconium Metal-Organic Frameworks
BORDIGA, Silvia;LAMBERTI, Carlo;
2014-01-01
Abstract
We report the structure of the Zr metalorganic frameworks (MOFs) UiO-66 and UiO-67 to very fine detail using synchrotron single-crystal X-ray diffraction and the synthesis method used to obtain single crystals. Zr terephthalate MOF UiO-66 is known to have missing linkers, and the nature of these are shown to be coordinating water and solvent molecules. Single crystals of the isoreticular material UiO-67 does not show such missing linker defects.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
14_UiO_66_67_XRD.pdf
Accesso riservato
Descrizione: Printed version
Tipo di file:
PDF EDITORIALE
Dimensione
2.28 MB
Formato
Adobe PDF
|
2.28 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
OpenAccess_UiO_66_67_SC_XRD.pdf
Open Access dal 03/10/2015
Descrizione: Open Access Post print version
Tipo di file:
POSTPRINT (VERSIONE FINALE DELL’AUTORE)
Dimensione
898 kB
Formato
Adobe PDF
|
898 kB | Adobe PDF | Visualizza/Apri |
Supporting_Info_cg501386j_si_005.pdf
Open Access dal 03/10/2015
Descrizione: Supporting Information
Tipo di file:
POSTPRINT (VERSIONE FINALE DELL’AUTORE)
Dimensione
1.05 MB
Formato
Adobe PDF
|
1.05 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.