The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.

Ca(BH4)2-Mg2NiH4: On the pathway to a Ca(BH4)2 system with a reversible hydrogen cycle

CHIEROTTI, Michele Remo;
2016

Abstract

The Ca(BH4)2–Mg2NiH4 system presented here is, to the best of our knowledge, the first described Ca(BH4)2-based hydride composite that reversibly transfers boron from the Ca-based compound(s) to the reaction partner. The ternary boride MgNi2.5B2 is formed upon dehydrogenation and the formation of Ca(BH4)2 upon rehydrogenation is confirmed.
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www.rsc.org/chemcomm
Chemistry (all); Catalysis; Ceramics and Composites; Electronic, Optical and Magnetic Materials; Surfaces, Coatings and Films; Materials Chemistry2506 Metals and Alloys; 2506
Bergemann, N; Pistidda, C.; Milanese, C.; Emmler, T.; Karimi, F.; Chaudhary, A.-L.; Chierotti, M.R.; Klassen, T.; Dornheim, M.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/1599028
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