Herein, we explore the possibility of functionalizing UiO-66 with the monoethanolamine (MEA) moiety. Several unsuccessful routes are discussed before we show that it can be achieved via a 2 stage post synthetic ligand exchange (PSE) reaction with a highly defective UiO-66 sample. The intermediate material is the most porous UiO-66 sample ever reported. We expect that this novel approach will allow many other functional moieties to be introduced.

Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66

VITILLO, Jenny Grazia;BORDIGA, Silvia;
2016-01-01

Abstract

Herein, we explore the possibility of functionalizing UiO-66 with the monoethanolamine (MEA) moiety. Several unsuccessful routes are discussed before we show that it can be achieved via a 2 stage post synthetic ligand exchange (PSE) reaction with a highly defective UiO-66 sample. The intermediate material is the most porous UiO-66 sample ever reported. We expect that this novel approach will allow many other functional moieties to be introduced.
2016
28
20
7190
7193
http://pubs.acs.org/doi/abs/10.1021/acs.chemmater.6b02749
Metallorganic Framework UiO-66; Post synthetic functionalization; Modulator
Shearer, Greig C.; Vitillo, Jenny G.; Bordiga, Silvia; Svelle, Stian; Olsbye, Unni; Lillerud, Karl Petter
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/1639950
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