Herein, we explore the possibility of functionalizing UiO-66 with the monoethanolamine (MEA) moiety. Several unsuccessful routes are discussed before we show that it can be achieved via a 2 stage post synthetic ligand exchange (PSE) reaction with a highly defective UiO-66 sample. The intermediate material is the most porous UiO-66 sample ever reported. We expect that this novel approach will allow many other functional moieties to be introduced.
Functionalizing the Defects: Postsynthetic Ligand Exchange in the Metal Organic Framework UiO-66
VITILLO, Jenny Grazia;BORDIGA, Silvia;
2016-01-01
Abstract
Herein, we explore the possibility of functionalizing UiO-66 with the monoethanolamine (MEA) moiety. Several unsuccessful routes are discussed before we show that it can be achieved via a 2 stage post synthetic ligand exchange (PSE) reaction with a highly defective UiO-66 sample. The intermediate material is the most porous UiO-66 sample ever reported. We expect that this novel approach will allow many other functional moieties to be introduced.
File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
Chem_Mat_FunctDefectUiO66.pdf
Accesso riservato
Descrizione: PDF editoriale
Tipo di file:
PDF EDITORIALE
Dimensione
976.84 kB
Formato
Adobe PDF
|
976.84 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
|
Chem_Mat_FunctDefectUiO66_Sup_Inf.pdf
Accesso aperto
Descrizione: Supporting Information
Tipo di file:
POSTPRINT (VERSIONE FINALE DELL’AUTORE)
Dimensione
5.71 MB
Formato
Adobe PDF
|
5.71 MB | Adobe PDF | Visualizza/Apri |
|
ChemMat_Funct_serine_OpenAccess.pdf
Open Access dal 11/09/2017
Descrizione: manoscritto
Tipo di file:
POSTPRINT (VERSIONE FINALE DELL’AUTORE)
Dimensione
835.71 kB
Formato
Adobe PDF
|
835.71 kB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
