In this chapter, we introduce MOFs as the new class of crystalline porous materials of remarkable potentialities. We underline the flexibility in the realization of different MOFs and the fact that they are ideal materials for performing X-ray absorption experiments at the metal K or L3 edges in transmission mode. A selection of relevant results appearing in the 2010-2016 period follows, highlighting the relevant role of both EXAFS and XANES in determining the structural and electronic configuration of metal centers inside MOFs.
Probing Structure and Reactivity of Metal Centers in Metal–Organic Frameworks by XAS Techniques
Borfecchia, Elisa;Braglia, Luca;Bonino, Francesca;Bordiga, Silvia;Lomachenko, Kirill A.;Lamberti, Carlo
2017-01-01
Abstract
In this chapter, we introduce MOFs as the new class of crystalline porous materials of remarkable potentialities. We underline the flexibility in the realization of different MOFs and the fact that they are ideal materials for performing X-ray absorption experiments at the metal K or L3 edges in transmission mode. A selection of relevant results appearing in the 2010-2016 period follows, highlighting the relevant role of both EXAFS and XANES in determining the structural and electronic configuration of metal centers inside MOFs.
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