In this chapter, we introduce MOFs as the new class of crystalline porous materials of remarkable potentialities. We underline the flexibility in the realization of different MOFs and the fact that they are ideal materials for performing X-ray absorption experiments at the metal K or L3 edges in transmission mode. A selection of relevant results appearing in the 2010-2016 period follows, highlighting the relevant role of both EXAFS and XANES in determining the structural and electronic configuration of metal centers inside MOFs.

Probing Structure and Reactivity of Metal Centers in Metal–Organic Frameworks by XAS Techniques

Borfecchia, Elisa;Braglia, Luca;Bonino, Francesca;Bordiga, Silvia;Lomachenko, Kirill A.;Lamberti, Carlo
2017-01-01

Abstract

In this chapter, we introduce MOFs as the new class of crystalline porous materials of remarkable potentialities. We underline the flexibility in the realization of different MOFs and the fact that they are ideal materials for performing X-ray absorption experiments at the metal K or L3 edges in transmission mode. A selection of relevant results appearing in the 2010-2016 period follows, highlighting the relevant role of both EXAFS and XANES in determining the structural and electronic configuration of metal centers inside MOFs.
2017
XAFS Techniques for Catalysts, Nanomaterials, and Surfaces
Iwasawa, Y.; Asakura, K.; Tada, M.
397
430
978-3-319-43864-1
978-3-319-43866-5
https://link.springer.com/chapter/10.1007/978-3-319-43866-5_26
MOF, EXAFS, XANES
Borfecchia, Elisa; Braglia, Luca; Bonino, Francesca; Bordiga, Silvia; Øien, Sigurd; Olsbye, Unni; Lillerud, Karl Petter; van Bokhoven, Jeroen A.; Loma...espandi
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/1658513
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