This perspective article aims to underline how cutting-edge synchrotron radiation spectroscopies such as extended X-ray absorption spectroscopy (EXAFS), X-ray absorption near edge structure (XANES), high resolution fluorescence detected (HRFD) XANES, X-ray emission spectroscopy (XES) and resonant inelastic X-ray scattering (RIXS) have played a key role in the structural and electronic characterization of Ti-based catalysts and photocatalysts, representing an important additional value to the outcomes of conventional laboratory spectroscopies (UV-Vis, IR, Raman, EPR, NMR etc.). Selected examples are taken from the authors research activity in the last two decades, covering both band-gap and shape engineered TiO2 materials and microporous titanosilicates (ETS-10, TS-1 and Ti-AlPO-5). The relevance of the state of the art simulation techniques as a support for experiments interpretation is underlined for all the reported examples.
Ti-Based Catalysts and Photocatalysts: Characterization and Modeling
Mino, Lorenzo;Signorile, Matteo;Crocellà, Valentina;Lamberti, Carlo
2019-01-01
Abstract
This perspective article aims to underline how cutting-edge synchrotron radiation spectroscopies such as extended X-ray absorption spectroscopy (EXAFS), X-ray absorption near edge structure (XANES), high resolution fluorescence detected (HRFD) XANES, X-ray emission spectroscopy (XES) and resonant inelastic X-ray scattering (RIXS) have played a key role in the structural and electronic characterization of Ti-based catalysts and photocatalysts, representing an important additional value to the outcomes of conventional laboratory spectroscopies (UV-Vis, IR, Raman, EPR, NMR etc.). Selected examples are taken from the authors research activity in the last two decades, covering both band-gap and shape engineered TiO2 materials and microporous titanosilicates (ETS-10, TS-1 and Ti-AlPO-5). The relevance of the state of the art simulation techniques as a support for experiments interpretation is underlined for all the reported examples.File | Dimensione | Formato | |
---|---|---|---|
Open access_Mino_ChemRec_2018.pdf
Open Access dal 22/12/2019
Descrizione: Articolo principale
Tipo di file:
POSTPRINT (VERSIONE FINALE DELL’AUTORE)
Dimensione
2.04 MB
Formato
Adobe PDF
|
2.04 MB | Adobe PDF | Visualizza/Apri |
Mino_ChemRec_2019.pdf
Accesso riservato
Descrizione: Articolo principale
Tipo di file:
PDF EDITORIALE
Dimensione
3.92 MB
Formato
Adobe PDF
|
3.92 MB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.