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EnglishElectron spins permeate every aspect of science and influence numerous chemical processes: they underpin transition metal chemistry and biochemistry, mediate photosynthesis and photovoltaics and are paramount in the field of quantum information, to name but a few. Electron paramagnetic resonance (EPR) spectroscopy detects unpaired electrons and provides detailed information on structure and bonding of paramagnetic species. In this tutorial review, aimed at non-specialists, we provide a theoretical framework and examples to illustrate the vast scope of the technique in chemical research. Case studies were chosen to exemplify systematically the different interactions that characterize a paramagnetic centre and to illustrate how EPR spectroscopy may be used to derive chemical information.
| Titolo: | Principles and applications of EPR spectroscopy in the chemical sciences | |
| Autori Riconosciuti: | ||
| Autori: | Roessler, Maxie M.; Salvadori, Enrico | |
| Data di pubblicazione: | 2018 | |
| Abstract: | Electron spins permeate every aspect of science and influence numerous chemical processes: they underpin transition metal chemistry and biochemistry, mediate photosynthesis and photovoltaics and are paramount in the field of quantum information, to name but a few. Electron paramagnetic resonance (EPR) spectroscopy detects unpaired electrons and provides detailed information on structure and bonding of paramagnetic species. In this tutorial review, aimed at non-specialists, we provide a theoretical framework and examples to illustrate the vast scope of the technique in chemical research. Case studies were chosen to exemplify systematically the different interactions that characterize a paramagnetic centre and to illustrate how EPR spectroscopy may be used to derive chemical information. | |
| Volume: | 47 | |
| Fascicolo: | 8 | |
| Pagina iniziale: | 2534 | |
| Pagina finale: | 2553 | |
| Digital Object Identifier (DOI): | 10.1039/c6cs00565a | |
| URL: | http://pubs.rsc.org/en/journals/journal/cs | |
| Parole Chiave: | Chemistry (all), EPR, electron spin | |
| Rivista: | CHEMICAL SOCIETY REVIEWS | |
| Appare nelle tipologie: | 03B-Review in Rivista / Rassegna della Lett. in Riv. / Nota Critica |
File in questo prodotto:
| File | Descrizione | Tipologia | Licenza | |
|---|---|---|---|---|
| c6cs00565a(3).pdf | published paper | PDF EDITORIALE | Utenti riconosciuti Richiedi una copia | |
| CSR_2018_Salvadori.pdf | preprint | PREPRINT (PRIMA BOZZA) | Open Access Visualizza/Apri |
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