Direct photolysis of contaminants in surface freshwaters, within the equivalent monochromatic wavelength (EMW) approximation

Abiotic photochemical reactions are usually very important degradation pathways for biorecalcitrant pollutants in surface freshwaters. Therefore, the assessment of photolytic lifetimes of contaminants helps estimate their impact on aquatic systems. This is commonly carried out by combining irradiation experiments and modelling, where the latter considers mathematical functions with polychromatic parameters, such as sunlight spectra, photolysis quantum yields (when Kasha's rule does not hold), and absorption coefficients. With the polychromatic approach, the photolytic lifetime is calculated by solving several integrals, which requires quite demanding modelling resources. In this work, we applied a recently developed approach, which is based on the equivalent monochromatic wavelength (EMW) approximation, to compute the direct-photolysis lifetimes of a range of >40 pollutants in inland waters. The EMW approximation allowed for easier modelling procedure, at the same time providing very good agreement with the polychromatic system. To further show EMW potentialities, lifetimes of three contaminants were mapped over the Piedmont region (NW Italy), as an example of how easy it becomes to geographically EMW-assess the potential of watercourses, to get photochemically decontaminated from pollutants.