Implications of garnet nucleation overstepping for the P-T evolution of the Lesser Himalayan Sequence of central Nepal

Recent studies have demonstrated that kinetic factors can significantly influence garnet nucleation, delaying its appearance with respect to the equilibrium predictions. Overstepping of garnet nucleation occurs in both contact and regional metamorphic settings, with extremely variable degrees: The factors controlling such highly variable degrees of overstepping are still unclear. This study focuses on garnet nucleation and growth in aluminous metapelites from the Barrovian inverted metamorphic pile of the upper portion of the Lesser Himalayan Sequence (Upper-LHS; central Nepal), with the aim of (i) investigating if (and how) the bulk-rock composition can influence overstepping of garnet nucleation and (ii) which are the implications of garnet nucleation overstepping for the P-T evolution of a Barrovian metamorphic sequence. Detailed petrographic, microstructural and compositional data are presented for six phyllitic schists, containing porphyroblasts of garnet, staurolite and/or kyanite. Their P-T evolution is constrained through thermodynamic forward modelling (i.e., isochemical phase diagrams combined with isopleth thermobarometry), assuming that equilibrium was attained at every stage of their metamorphic evolution. Comparison between the P-T conditions inferred for the growth of garnet core, the assemblages predicted to be stable at these P-T conditions and the modelled garnet-in reaction boundary suggests that the studied samples have experienced different degrees of apparent thermal (Delta T) and/or baric (Delta P) overstepping of garnet nucleation. We suggest that the bulk-rock MnO and CaO amounts might have influenced the apparent Delta T and Delta P overstepping of the garnet-in reaction: more specifically, the higher the bulk-rock MnO content, the more pronounced the apparent Delta T overstepping, whereas the lower the bulk-rock CaO content, the greater the Delta P overstepping. However, rather than an effective delay of garnet appearance with respect to equilibrium predictions, the apparent Delta T overstepping of garnet nucleation could reflect the attainment of the critical 0.5% threshold of garnet abundance, below which garnet is not readily detected in thin section. Kinetic factors seem much less critical in controlling the growth of the garnet rim at peak P-T conditions, confirming that peak metamorphic conditions constrained through equilibrium approaches based on the composition of garnet rim and of the matrix assemblage can be considered as reliable. Overall, the P-T paths of the studied samples are characterized by prograde heating coupled with tectonic overload (peak-P conditions of 9.5-10.5 kbar, 580-590 degrees C), followed by heating during exhumation (peak-T conditions of 8.2-8.9 kbar, 610-630 degrees C), supporting those thermo-mechanical models that predict a period of slowdown (or quiescence) of the Main Central Thrust activity.