Possible Effects of Changes in Carbonate Concentration and River Flow Rate on Photochemical Reactions in Temperate Aquatic Environments

In temperate environments, climate change could affect water pH by inducing enhanced dissolution of CaSO4 followed by biological sulphate reduction, with the potential to basify water due to H+ consumption. At the same time, increased atmospheric CO2 could enhance weathering of carbonate rocks (e.g., dolomite) and increase the total concentration of dissolved carbonate species. Both processes enhance phototransformation by the carbonate radical (CO3•−), as shown for the non-steroidal anti-inflammatory drug paracetamol, provided that the dissolved organic carbon of water does not undergo important fluctuations. Climate change could also affect hydrology, and prolonged drought periods might considerably decrease flow rates in rivers. This is a substantial problem because wastewater pollutants become less diluted and, as a result, can exert more harmful effects due to increased concentrations. At the same time, in low-flow conditions, water is also shallower and its flow velocity is decreased. Photochemical reactions become faster because shallow water is efficiently illuminated by sunlight, and they also have more time to occur because water takes longer to cover the same river stretch. As a result, photodegradation of contaminants is enhanced, which offsets lower dilution but only at a sufficient distance from the wastewater outlet; this is because photoreactions need time (which translates into space for a flowing river) to attenuate pollution.