Potentially toxic elements and lead isotopic signatures in the 10 μm fraction of urban dust: Environmental risk enhanced by resuspension of contaminated soils

In urban environments, soils are a sink of pollutants and might become a source of contamination, as they commonly display potentially toxic elements (PTE) concentrations above the legislative limits. Particularly, the inhalable fraction of soils (<10 μm) is enriched in PTE compared to bulk soils (BS). The enrichment makes these particles an environmental hazard because of their susceptibility to resuspension and their potential contribution to road dust (RD) and atmospheric particulate matter (PM10) pollution. To gain a better insight into urban contamination dynamics we studied the BS, the resuspended <10 μm fraction of BS (Res-BS) and RD (Res-RD) in a European historically industrialized and densely populated city. Compared to BS, the Res-BS and Res-RD showed higher PTE concentrations and a higher variability for most of the elements. Lead was the only PTE showing similar concentrations in all the matrices, suggesting shared sources and redistribution pathways within the city. Chemometric elaborations identified Res-BS as a transition between BS and Res-RD or, rather, a Res-RD precursor. Also, Pb was confirmed to be ubiquitous in all the media. In all the matrices, Pb isotopic signatures were investigated and compared with PM10 fingerprints from the same city. The anthropogenic isotopic signature in Res-BS and Res-RD was evident, and samples belonging to neighboring sites showed comparable isotopic ratios. The Res-BS appeared as a key driver for Pb distribution within the city both in Res-RD and in PM10. These results demonstrate the intimate interaction between urban environmental compartments (soil, road dust and PM10), and the active contribution of fine soil fractions to anthropogenic pollution, with relevant policy implications in urban areas since soils were found to contribute directly to air pollution.