Cu-zeolites are found to activate the C-H bond of ethane already at 150 °C in a cyclic protocol and form ethylene with a high selectivity. Both the zeolite topology and Cu content are found to impact the ethylene yield. Ethylene adsorption studies with FT-IR, demonstrate that oligomerization of ethylene occurs over protonic zeolites, while this reaction does not occur over Cu-zeolites. We postulate that this observation is the origin of the high ethylene selectivity. Based on the experimental results, we propose that the reaction proceeds via the formation of an ethoxy intermediate.
Cu-loaded zeolites enable the selective activation of ethane to ethylene at low temperatures and pressure
Bordiga, Silvia;Borfecchia, Elisa;
2023-01-01
Abstract
Cu-zeolites are found to activate the C-H bond of ethane already at 150 °C in a cyclic protocol and form ethylene with a high selectivity. Both the zeolite topology and Cu content are found to impact the ethylene yield. Ethylene adsorption studies with FT-IR, demonstrate that oligomerization of ethylene occurs over protonic zeolites, while this reaction does not occur over Cu-zeolites. We postulate that this observation is the origin of the high ethylene selectivity. Based on the experimental results, we propose that the reaction proceeds via the formation of an ethoxy intermediate.File in questo prodotto:
File | Dimensione | Formato | |
---|---|---|---|
23-Kvande_ChemComm_EthaneToEtylene_Cuzeo_edit_OA.pdf
Accesso aperto
Descrizione: pdf editoriale open access
Tipo di file:
PDF EDITORIALE
Dimensione
1.21 MB
Formato
Adobe PDF
|
1.21 MB | Adobe PDF | Visualizza/Apri |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.