Unraveling the dealloying mechanism of a Au33Fe67 metastable precursor for a low-cost nanoporous gold production

A low-cost Nanoporous Gold (NPG) has been successfully prepared by chemical dealloying of a Au33Fe67 supersaturated solid solution, whose ribbons were obtained by rapid solidification using melt-spinning technique. The dealloying procedures were carried out in 1 M HNO3 at 70 °C for varying durations. As-quenched ribbon and dealloyed samples have been structurally and compositionally investigated using XRD, FESEM and EDS techniques. The obtained NPG is homogeneous with tunable ligament size and shape, easy-to-handle and free-standing. Most notably, a metastable precursor has been favourably obtained from an immiscible Au-Fe system. Furthermore, according to the characterization results, a mechanism of dealloying has been proposed. Pairing Au with cheap and abundant Fe and fabricating an Fe-rich precursor gives an exceedingly cost-effective starting material. No usage of critical raw materials is involved. Then, employing a straight-forward and rapid dealloying procedure to obtain the NPG sample, makes for an overall inexpensive and sustainable production.