Vapour digestion of a mixture of solid [Fe(eta(5)-C5H4-C5H4N)(2)] and solid pimelic acid HOOC(CH2)(5)COOH in the presence of solvent vapours generates co-crystals of different stoichiometry depending on the protic or aprotic nature of the solvent. The nature of the products has been ascertained by a combined use of SSNMR and X-ray diffraction.
Solvent effect in a "solvent free" reaction
CHIEROTTI, Michele Remo;GOBETTO, Roberto;
2007-01-01
Abstract
Vapour digestion of a mixture of solid [Fe(eta(5)-C5H4-C5H4N)(2)] and solid pimelic acid HOOC(CH2)(5)COOH in the presence of solvent vapours generates co-crystals of different stoichiometry depending on the protic or aprotic nature of the solvent. The nature of the products has been ascertained by a combined use of SSNMR and X-ray diffraction.
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