The reaction of Ru-3(CO)(6)(mu-CO)(mu(3):eta(2):eta(3):eta(5)-C12H8) (physisorbed on SiO2) with CO in the solid state leads to Ru-3(CO)(12) and acenaphthylene in quantitative yields; the Ru-3(CO)(12) generated in situ is highly mobile leading to a reduced chemical shielding anisotropy.
Enhanced mobility of the cluster Ru-3(CO)(12) in the solid state formed in situ by the reaction of CO and Ru-3(CO)(6)(mu-CO)(mu(3):eta 2 :eta 3 :eta 5-C12H8) on silica
AIME, Silvio;GOBETTO, Roberto;
2000-01-01
Abstract
The reaction of Ru-3(CO)(6)(mu-CO)(mu(3):eta(2):eta(3):eta(5)-C12H8) (physisorbed on SiO2) with CO in the solid state leads to Ru-3(CO)(12) and acenaphthylene in quantitative yields; the Ru-3(CO)(12) generated in situ is highly mobile leading to a reduced chemical shielding anisotropy.
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