Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

Detection of a novel intermediate in the addition of thiols to osmium carbonyl clusters

GOBETTO, Roberto;AIME, Silvio;
1998-01-01

Abstract

Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.
1998
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2721
2722
AGOSTIC INTERACTION; OSMIUM; CLUSTERS; RELAXATION; NMR
Kiriakidou, K; Plutino, Mr; Prestopino, F; Monari, M; Johansson, M; Elding, Li; Valls, E; Gobetto, Roberto; Aime, Silvio; Nordlander, E.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/25225
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