We describe herein the synthesis and the electrochemical behaviour of a series of bis( ferrocenylethynyl) complexes of platinum( II). In all complexes, the electronic interaction between the redox-active iron cores of the ferrocenyl termini is small, indicating a moderate electronic delocalisation over the bis( cyclopentadienyl-acetylide) Pt chain. (C) 1998 Elsevier Science S.A. All rights reserved.
Synthesis and characterisation of bis(ferrocenylethynyl) complexes of platinum(II) - A re-investigation of their electrochemical behaviour
GOBETTO, Roberto;NERVI, Carlo;
1998-01-01
Abstract
We describe herein the synthesis and the electrochemical behaviour of a series of bis( ferrocenylethynyl) complexes of platinum( II). In all complexes, the electronic interaction between the redox-active iron cores of the ferrocenyl termini is small, indicating a moderate electronic delocalisation over the bis( cyclopentadienyl-acetylide) Pt chain. (C) 1998 Elsevier Science S.A. All rights reserved.
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