Alkynes react at low temperature with [RU(3)H(mu-H)(CO)(11)] to afford the novel [Ru-3(CO)(11)(alkyne)] complexes, which correspond to the first stage of the coordination of alkynes to metal-clusters and are the precursors of the previously reported [Ru-3(CO)(9)(mu-CO)(mu(3)-eta(2)-alkyne)] derivatives.

A versatile route to [Ru-3(CO)(11)(alkyne)] complexes

AIME, Silvio;DASTRU', Walter;GOBETTO, Roberto;MILONE, Luciano;VIALE, Alessandra
1997

Abstract

Alkynes react at low temperature with [RU(3)H(mu-H)(CO)(11)] to afford the novel [Ru-3(CO)(11)(alkyne)] complexes, which correspond to the first stage of the coordination of alkynes to metal-clusters and are the precursors of the previously reported [Ru-3(CO)(9)(mu-CO)(mu(3)-eta(2)-alkyne)] derivatives.
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CRYSTAL; ALKYNES; CLUSTERS; REACTIVE INTERMEDIATES
AIME S; DASTRU W; R. GOBETTO; MILONE L; VIALE A
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/25248
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