A disperse and a disperse/reactive azo-dyes were prepared and characterised with spectroscopic methods. The complexes with beta-cyclodextrin were prepared by a dry milling method. The characterisation of the complexes in solid state was performed by C-13 CP MAS NMR, FT-IR, Raman spectroscopies and TGA-DTA analysis. The presence of the complexes in solution was evidenced with ESI-MS experiments. The products were used to dye synthetic (nylon, PET), natural (cotton) and cotton-PET blend fibres. Colour intensity and uniformity were evaluated by means of tristimulous colorimetry. beta-Cyclodextrin, used as additive in dyeing baths, enhanced the colour intensity and uniformity of dyed samples. The complexes gave rise to a generalised good result. The disperse/reactive dye showed better fastness to washing properties on nylon 6 and cotton fibres. beta-Cyclodextrin easily substituted the surface active agents, normally used in industrially dyeing processes, without loss in dyeing quality as dyeing uniformity, intensity and washing fastness.
Preparation and application of a β-cyclodextrin-disperse/reactive dye complex
PARLATI, Stefania;GOBETTO, Roberto;BAROLO, CLAUDIA;ARRAIS, Aldo;BUSCAINO, Roberto;MEDANA, Claudio;SAVARINO, Piero
2007-01-01
Abstract
A disperse and a disperse/reactive azo-dyes were prepared and characterised with spectroscopic methods. The complexes with beta-cyclodextrin were prepared by a dry milling method. The characterisation of the complexes in solid state was performed by C-13 CP MAS NMR, FT-IR, Raman spectroscopies and TGA-DTA analysis. The presence of the complexes in solution was evidenced with ESI-MS experiments. The products were used to dye synthetic (nylon, PET), natural (cotton) and cotton-PET blend fibres. Colour intensity and uniformity were evaluated by means of tristimulous colorimetry. beta-Cyclodextrin, used as additive in dyeing baths, enhanced the colour intensity and uniformity of dyed samples. The complexes gave rise to a generalised good result. The disperse/reactive dye showed better fastness to washing properties on nylon 6 and cotton fibres. beta-Cyclodextrin easily substituted the surface active agents, normally used in industrially dyeing processes, without loss in dyeing quality as dyeing uniformity, intensity and washing fastness.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.