Mesoporous aluminophosphates (ALPO) was synthesised using cetyltrimethylammonium bromide (CTMABr) as a structure-directing agent, phosphoric acid and aluminum sulfate as sources of structure elements. Ti(IV) ions were introduced into mesoporous ALPO by grafting titanocene dichloride, [Cp2TiCl2], onto the P-OH and Al-OH groups exposed in the channels. FTIR spectroscopy was used to study surface hydroxyls, and by the use of NH3 as molecular probe, to assess the surface acidity of both meso-ALPO and meso-Ti-ALPO materials. The coordination of Ti(IV) centres in Ti-ALPO material was studied using DR UV-Vis spectroscopy.

Synthesis and surface properties of Ti-containing mesoporous aluminophosphates. A comparison with Ti-grafted mesoporous silica Ti-MCM-41

GIANOTTI, Enrica;COLUCCIA, Salvatore;
2003-01-01

Abstract

Mesoporous aluminophosphates (ALPO) was synthesised using cetyltrimethylammonium bromide (CTMABr) as a structure-directing agent, phosphoric acid and aluminum sulfate as sources of structure elements. Ti(IV) ions were introduced into mesoporous ALPO by grafting titanocene dichloride, [Cp2TiCl2], onto the P-OH and Al-OH groups exposed in the channels. FTIR spectroscopy was used to study surface hydroxyls, and by the use of NH3 as molecular probe, to assess the surface acidity of both meso-ALPO and meso-Ti-ALPO materials. The coordination of Ti(IV) centres in Ti-ALPO material was studied using DR UV-Vis spectroscopy.
2003
349
259
264
mesostructures; aluminophosphates; titanium-aluminophosphates; FTIR spectroscopy; surface acidity; DR UV-Vis spectroscopy
E. GIANOTTI; E.C. OLIVEIRA; S. COLUCCIA; H.O. PASTORE; L. MARCHESE
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/3703
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