Quantitative determination of gold active sites by chemisorption and by infrared measurements of adsorbed CO.

Quantitative measurements of CO chemisorption in the range 140–180 K, supported by FTIR data on adsorbed CO, were performed on Au/TiO2, Au/Fe2O3, and Au/CeO2 catalysts. On the first two samples, which had similar particle size distributions, an average Au/CO chemisorption stoichiometry of about 3, referred to step-edge Au atoms, was found. On Au/CeO2, where very small clusters and quite large particles are present, the CO-chemisorbed volume was much higher than expected, due to the prevailing contribution of very small Au clusters. On the same sample, a change in the IR absorption coefficient was observed and was reasonably explained.