The adsorption of hydrogen on H-Y and Pd(0)-H-Y zeolites was investigated by IR (in the 300-20 K temperature range) and EXAFS spectroscopies and the energy barriers for diffusion of hydrogen in the internal voids of the faujasite structure evaluated by ab initio calculations. On H-Y, H-2 is adsorbed at 20 K inside the super-cages giving rise to 1:1 -OH center dot center dot center dot H-2 hydrogen bonded complexes with the Bronsted acid groups, as well as less specific interaction with the cage walls. Due to the high energy barrier for crossing the framework hexagonal apertures, H-2 cannot enter the sodalite-cages. On Pd(0) containing zeolites, characterized as far the dispersion of the metal is concerned by TEM, EXAFS and IR spectroscopy of adsorbed CO, hydrogen is adsorbed in atomic form to give a metal-hydride phase; subsequent spill-over effects allow confinement of hydrogen also in the small sodalite-cages, as demonstrated by H/D isotopic substitution experiments.

Hydrogen adsorption and spill-over effects on H-Y and Pd-containing Y zeolites - An experimental and theoretical investigation

SCARANO, Domenica;BORDIGA, Silvia;LAMBERTI, Carlo;RICCHIARDI, Gabriele;SPOTO, Giuseppe
2006-01-01

Abstract

The adsorption of hydrogen on H-Y and Pd(0)-H-Y zeolites was investigated by IR (in the 300-20 K temperature range) and EXAFS spectroscopies and the energy barriers for diffusion of hydrogen in the internal voids of the faujasite structure evaluated by ab initio calculations. On H-Y, H-2 is adsorbed at 20 K inside the super-cages giving rise to 1:1 -OH center dot center dot center dot H-2 hydrogen bonded complexes with the Bronsted acid groups, as well as less specific interaction with the cage walls. Due to the high energy barrier for crossing the framework hexagonal apertures, H-2 cannot enter the sodalite-cages. On Pd(0) containing zeolites, characterized as far the dispersion of the metal is concerned by TEM, EXAFS and IR spectroscopy of adsorbed CO, hydrogen is adsorbed in atomic form to give a metal-hydride phase; subsequent spill-over effects allow confinement of hydrogen also in the small sodalite-cages, as demonstrated by H/D isotopic substitution experiments.
2006
307(1)
3
12
http://www.sciencedirect.com/science?_ob=ArticleURL&_udi=B6TF5-4JT3S24-2&_user=525216&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_acct=C000026382&_version=1&_urlVersion=0&_userid=525216&md5=f0ea26120dc1bf1100c1e5283484b6e6
H-Y zeolites; Pd(0)-H-Y zeolites; spill-over effect; IR; EXAFS; ab initio calculations
D. SCARANO; S. BORDIGA; C. LAMBERTI; G. RICCHIARDI; S. BERTARIONE; G. SPOTO
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/40562
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