The electrochemical behaviour of the [Co-2(CO)(6)](2)(mu-R-C=C-L-C=C-R) and [Co-2(CO)(4)(dppm)](2)(mu-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.
Electronic communication in [Co-2(CO)(6)](2)-diyne and [Co-2(CO)(4)(dppm)](2)-diyne complexes
OSELLA, Domenico;MILONE, Luciano;NERVI, Carlo;RAVERA, Mauro
1998-01-01
Abstract
The electrochemical behaviour of the [Co-2(CO)(6)](2)(mu-R-C=C-L-C=C-R) and [Co-2(CO)(4)(dppm)](2)(mu-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.
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