The electrochemical behaviour of the [Co-2(CO)(6)](2)(mu-R-C=C-L-C=C-R) and [Co-2(CO)(4)(dppm)](2)(mu-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.

Electronic communication in [Co-2(CO)(6)](2)-diyne and [Co-2(CO)(4)(dppm)](2)-diyne complexes

OSELLA, Domenico;MILONE, Luciano;NERVI, Carlo;RAVERA, Mauro
1998

Abstract

The electrochemical behaviour of the [Co-2(CO)(6)](2)(mu-R-C=C-L-C=C-R) and [Co-2(CO)(4)(dppm)](2)(mu-R-C=C-L-C=C-R) series is reported. Qualitative evidence suggests that both through-space and through-bond interactions are operating with different relative weight depending on the spacer L.
-
1473
1477
electrochemistry; mixed-valent compounds; alkynecobalt complexes; through-bond interactions; through-space interactions; PARAMAGNETIC ORGANOMETALLIC MOLECULES; X-RAY STRUCTURES; ELECTROCHEMICAL-BEHAVIOR; VOLTAMMETRY; CARBON; COBALT; ALKYNE; R2C2CO2(CO)6; CONVOLUTION; REACTIVITY
D. Osella; L. Milone; C. Nervi; M. Ravera
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/44975
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 47
  • ???jsp.display-item.citation.isi??? 47
social impact