Cyclodextrins act as inverse phase transfer catalysts in the oxidation of methyl ketones by hypochloride (the haloform reaction). The reaction is affected by the choice and the amount of cyclodextrin. The reaction proceeds under mild reaction conditions and it provides only the corresponding carboxylic acid as reaction product. No organic solvent is required.
The Haloform Reaction in the Presence of Cyclodextrins
TROTTA, Francesco;ZANETTI, Marco
2000-01-01
Abstract
Cyclodextrins act as inverse phase transfer catalysts in the oxidation of methyl ketones by hypochloride (the haloform reaction). The reaction is affected by the choice and the amount of cyclodextrin. The reaction proceeds under mild reaction conditions and it provides only the corresponding carboxylic acid as reaction product. No organic solvent is required.
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