The addition of CH3CHO to a chloroform solution of H(mu-H)Os-3(CO)(10)(NH3) affords the new H(mu-H)Os-3(CO)(10)(HN=CHCH3) derivative where the imine ligand occupies a terminal position. The stereochemistry of the adduct appears to be determined by the occurrence of an unconventional hydrogen-bond interaction involving the N-H moiety and the terminal hydride.
Coordination of an Imine Ligand on an Os3 Cluster Stabilized by Intramolecular Os-H--H-N Hydrogen Bonding
AIME, Silvio;GOBETTO, Roberto;
1999-01-01
Abstract
The addition of CH3CHO to a chloroform solution of H(mu-H)Os-3(CO)(10)(NH3) affords the new H(mu-H)Os-3(CO)(10)(HN=CHCH3) derivative where the imine ligand occupies a terminal position. The stereochemistry of the adduct appears to be determined by the occurrence of an unconventional hydrogen-bond interaction involving the N-H moiety and the terminal hydride.
File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
