A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous d phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.

Storage of hydrogen as a guest of a nanoporous polymeric crystalline phase

ZAVOROTYNSKA, Olena;VITILLO, Jenny Grazia;ZECCHINA, Adriano;SPOTO, Giuseppe
2010

Abstract

A mechanism of H2 uptake, based on adsorption in the ordered cavities of nanoporous polymeric crystalline phases rather than on disordered amorphous polymeric surfaces, has been clearly established, for aerogels of syndiotactic polystyrene (s-PS) exhibiting the nanoporous d phase. An ordered arrangement of the H2 molecules is proven by FTIR spectra while the inclusion of H2 is assessed by gravimetric measurements and molecular simulations.
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http://pubs.rsc.org/en/Content/ArticleLanding/2010/CP/b923173k
Hydrogen storage; Nanoporous materials; Polymers; FTIR; Gravimetric methods; Gran Canonical Monte Carlo
Susana Figueroa-Gerstenmaier; Cristophe Daniel; Giuseppe Milano; Gaetano Guerra; Olena Zavorotynska; Jenny G. Vitillo; Adriano Zecchina; Giuseppe Spoto
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/77969
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