The hydrogen storage properties of Mg-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework possessing hexagonal one-dimensional channels decorated with unsaturated Mg2+ coordination sites, have been examined through low-and high-pressure adsorption experiments, infrared spectroscopy, and neutron scattering studies.
Hydrogen storage properties and neutron scattering studies of Mg-2(dobdc)-a metal-organic framework with open Mg2+ adsorption sites
CHAVAN, SACHIN MARUTI;BORDIGA, Silvia;
2011-01-01
Abstract
The hydrogen storage properties of Mg-2(dobdc) (dobdc(4-) = 2,5-dioxido-1,4-benzenedicarboxylate), a metal-organic framework possessing hexagonal one-dimensional channels decorated with unsaturated Mg2+ coordination sites, have been examined through low-and high-pressure adsorption experiments, infrared spectroscopy, and neutron scattering studies.
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