The products of the reaction between Os3(CO)10(NCMe)2 and benzotriazole, a widely used corrosion inhibitor, are discussed in the light of their spectroscopic data. The structural, chemical and electrochemical properties of these molecular clusters are considered, with the aim of providing new insights into the actual mechanism of protection of metallic surfaces from corrosion.
Organomental clusters as models for corrosion inhibitors. The reaction of Os3(CO)10(NCCH3)2 with benzotriazole
AIME, Silvio;GOBETTO, Roberto;
1988-01-01
Abstract
The products of the reaction between Os3(CO)10(NCMe)2 and benzotriazole, a widely used corrosion inhibitor, are discussed in the light of their spectroscopic data. The structural, chemical and electrochemical properties of these molecular clusters are considered, with the aim of providing new insights into the actual mechanism of protection of metallic surfaces from corrosion.
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