The combined use of 13C and 17O spin–lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.
Carbon-13 and oxygen-17 nuclear magnetic resonance relaxation studies of [M3(CO)12] derivatives (M = Fe, Ru, or Os)
AIME, Silvio;GOBETTO, Roberto;
1988-01-01
Abstract
The combined use of 13C and 17O spin–lattice relaxation times for co-ordinated carbonyl ligands in [M3(CO)12] clusters (M = Fe, Ru, or Os) allows the determination of 17O quadrupolar coupling constants and the correlation times for molecular tumbling at different temperatures.
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