A novel bifunctional linker mol., bis(4-​mercaptophenyl)​phosphinic acid, is designed to be used in a QDs solar cells. The linker anchors to TiO2 mesoporous film through the phosphinic acid functional group and to the PbS QDs through the two thiol groups. The way of attachment of this new linker mol. in a photovoltaic PbS QDs​/TiO2 mesoporous device was studied by FTIR measurements. The photovoltaic performance of this new linker in a heterojunction PbS QDs solar cell show high Voc relative to QDs based solar cells, which will allow to receive high power conversion efficiency using this novel designed linker. This novel bifunctional linker mol. should pave the way for enhancing binding strength, and efficiency of QDs solar cells compared to the state-​of-​the-​art linkers.

Design and Development of Novel Linker for PbS Quantum Dots/TiO2Mesoscopic Solar cell

PARK, JINHYUNG;BAROLO, CLAUDIA;VISCARDI, Guido;
2011-01-01

Abstract

A novel bifunctional linker mol., bis(4-​mercaptophenyl)​phosphinic acid, is designed to be used in a QDs solar cells. The linker anchors to TiO2 mesoporous film through the phosphinic acid functional group and to the PbS QDs through the two thiol groups. The way of attachment of this new linker mol. in a photovoltaic PbS QDs​/TiO2 mesoporous device was studied by FTIR measurements. The photovoltaic performance of this new linker in a heterojunction PbS QDs solar cell show high Voc relative to QDs based solar cells, which will allow to receive high power conversion efficiency using this novel designed linker. This novel bifunctional linker mol. should pave the way for enhancing binding strength, and efficiency of QDs solar cells compared to the state-​of-​the-​art linkers.
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3264
3267
http://pubs.acs.org/journal/aamick
mesoporous TiO2; PbS; phosphinic acid; heterojunction solar cells; bifunctional molecular linker; quantum dots
Lioz Etgar; JinHyung Park; Claudia Barolo; Md. K. Nazeeruddin; Guido Viscardi; Michael Graetzel
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/90136
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