Influence of structure on the thermal properties of a large group of natural and synthetic porphyrins (H2P) and metalloporphyrins (MP) was analyzed on the ground of thermogravimetric studies. The initial stage of thermal degradation of “classical” porphyrin containing a flat or pseudo-planar macrocycle is a result of oxidative degradation of the macrocyclic structure with the formation of linear tetrapyrrols. The negative effect on the thermal stability of porphyrins exerts the violation of the planar structure of the macrocycle, and the presence of bulky alkyl and polar pseudoalkyl substituents. In many cases, the general trend in the decrease in the stability of metalloporphyrins (MP) in comparison with the corresponding H2P is a consequence of intramolecular metal ↔ ligand redox processes.

Oxidativ destruction of porphyrins and metal porphyrins in polythermal conditions.

BALANTSEVA, ELENA;
2011

Abstract

Influence of structure on the thermal properties of a large group of natural and synthetic porphyrins (H2P) and metalloporphyrins (MP) was analyzed on the ground of thermogravimetric studies. The initial stage of thermal degradation of “classical” porphyrin containing a flat or pseudo-planar macrocycle is a result of oxidative degradation of the macrocyclic structure with the formation of linear tetrapyrrols. The negative effect on the thermal stability of porphyrins exerts the violation of the planar structure of the macrocycle, and the presence of bulky alkyl and polar pseudoalkyl substituents. In many cases, the general trend in the decrease in the stability of metalloporphyrins (MP) in comparison with the corresponding H2P is a consequence of intramolecular metal ↔ ligand redox processes.
81
1222
1230
http://www.springer.com/chemistry/journal/11176
porphyrin complexes; thermal analysis; metalloporphyrins; tharmal stability
Antina Е.V.; Balantseva Е.V.; Berezin М.B.
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Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/117628
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