The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.

A spectroscopic and computational study of a tough MOF with a fragile linker: Ce-UiO-66-ADC.

Alessia Airi;Cesare Atzori;Francesca Bonino;Alessandro Damin;Silvia Bordiga
2020-01-01

Abstract

The thermolabile acetylene dicarboxylic acid has been introduced as linker in UiO-66 topology, synthetizing the compound with formula [Ce6O4(OH)4(ADC)6] and denoted as Ce-UiO-66-ADC MOF. The characterization by multi-technique approach coupled with computational modelling revealed a peculiar intrinsic defective nature related to the nature of the linker.
2020
49
12
16
https://pubs.rsc.org/en/content/articlelanding/2020/DT/C9DT04112E#!divAbstract
MOF, IR spectroscopy, Raman spectroscopy, DFT, Cerium, MOF synthesis, MOF characterization
Alessia Airi, Cesare Atzori, Francesca Bonino, Alessandro Damin, Sigurd Øien-Ødegaard, Erlend Aunan, Silvia Bordiga
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/1723836
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