A representative library of 3-(a-aryl)alkenylindoles has been prepared via a Brønsted-acid catalysed dehydrative coupling reaction between alkyl aryl ketones and some indoles. An interesting diastereoselectivity has been observed and has been explained from a mechanistic point of view.
Diastereoselective synthesis of 3-(a-aryl)alkenylindoles from the direct dehydrative coupling of indoles and ketones: A synthetic and theoretical study.
Margherita Barbero;Domenica Marabello;Stefano Dughera;Achille Antenucci;Giovanni Ghigo
2020-01-01
Abstract
A representative library of 3-(a-aryl)alkenylindoles has been prepared via a Brønsted-acid catalysed dehydrative coupling reaction between alkyl aryl ketones and some indoles. An interesting diastereoselectivity has been observed and has been explained from a mechanistic point of view.
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