In a series of organometallic carbonyl complexes, hydride ligands which experience weak dipolar interactions and other ligands (tert-butyl, NH3) which have dipolar interactions moderated by intramolecular motion in the solid state give well resolved solid state H-1 MAS NMR spectra. This establishes solid state H-1 NMR as a valuble structural tool, without the need for multiple pulse data acquisition or the need to employ H-2 substitution.
H-1 MAS NMR-SPECTRA OF TRANSITION-METAL CARBONYL HYDRIDES
AIME, Silvio;GOBETTO, Roberto;
1995-01-01
Abstract
In a series of organometallic carbonyl complexes, hydride ligands which experience weak dipolar interactions and other ligands (tert-butyl, NH3) which have dipolar interactions moderated by intramolecular motion in the solid state give well resolved solid state H-1 MAS NMR spectra. This establishes solid state H-1 NMR as a valuble structural tool, without the need for multiple pulse data acquisition or the need to employ H-2 substitution.
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