Corrols (H3Cor) attract the attention of researchers not only as structural analogues of porphyrins (H2P) and Corrins, but also as promising catalysts, materials with nonlinear optical properties and agents for photodynamic therapy. One of the important criteria for their practical application is the stability of compounds in different environments. Therefore, an resistance to thermal destruction of meso-phenyl-substituted ligand H3(ms-Ph)3Cor has been studied by thermogravimetric method. This compound exhibits a tendency, in contrast to the H2P to stabilize metals in high oxidation states, as well as complexes with Mn (III), Co (III), Cu (III) and Zn (II).

Comparative characteristics of the thermal stability of meso-substituted corrols, porphyrins, and their metal complexes

BALANTSEVA, ELENA;
2009

Abstract

Corrols (H3Cor) attract the attention of researchers not only as structural analogues of porphyrins (H2P) and Corrins, but also as promising catalysts, materials with nonlinear optical properties and agents for photodynamic therapy. One of the important criteria for their practical application is the stability of compounds in different environments. Therefore, an resistance to thermal destruction of meso-phenyl-substituted ligand H3(ms-Ph)3Cor has been studied by thermogravimetric method. This compound exhibits a tendency, in contrast to the H2P to stabilize metals in high oxidation states, as well as complexes with Mn (III), Co (III), Cu (III) and Zn (II).
XXIV International Chugaev´s Conference of coordination chemistry
St.-Petersburg
15–19 June
XXIV International Chugaev´s Conference of coordination chemistry
Kuznetsov N.T.
234
235
9785852630261
http://www.onlinereg.ru/chugaev
thermal analysis; corrol; porphyrin; metal complexes
Berezin B.D.; Karimov D.R.; Balantseva E.V.; Jutanova S.L.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: http://hdl.handle.net/2318/78610
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact