A deep eutectic solvent (DES) based on glycerol and KF is successfully exploited as a solvent medium in Ullmann homocoupling of arenediazonium salts. The reactions were carried out in mild conditions and target products were obtained in fairly good yields. A computational study is presented aiming to understand the reaction mechanism and Raman spectroscopy is employed as an experimental tool to support it.

Ullmann homocoupling of arenediazonium salts in a deep eutectic solvent. Synthetic and mechanistic aspects

Ghigo, G
First
;
Bonomo, M
;
Antenucci, A;Damin, A;Dughera, S
Last
2022-01-01

Abstract

A deep eutectic solvent (DES) based on glycerol and KF is successfully exploited as a solvent medium in Ullmann homocoupling of arenediazonium salts. The reactions were carried out in mild conditions and target products were obtained in fairly good yields. A computational study is presented aiming to understand the reaction mechanism and Raman spectroscopy is employed as an experimental tool to support it.
2022
12
41
26640
26647
https://pubs.rsc.org/en/content/articlelanding/2022/RA/D2RA05272E
Ghigo, G; Bonomo, M; Antenucci, A; Damin, A; Dughera, S
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/2318/1875503
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